Electrochemistry in Near-Critical and Supercritical Fluids. I. Ammonia.

Abstract

Cyclic voltammetric and chronocoulometric studies of NH3 containing 0.1 - 0.2 M KI at T and P up to 160 c and 272 atm are reported. Electrochemical generation of solvated electrons is possible even under supercritical conditions, but their stability is lower at higher T. Reduction of m-chloronitrobenzene (MCNB) to the radical anion yields essentially Nernstian waves from 55 C to 160 C.

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Document Details

Document Type
Technical Report
Publication Date
Jul 18, 1984
Accession Number
ADA146429

Entities

People

  • Allen J. Bard
  • F. F. Fan
  • R. M. Crooks

Organizations

  • University of Texas at Austin

Tags

DTIC Thesaurus Topics

  • Aromatic Hydrocarbons
  • Cells
  • Chemistry
  • Critical Temperature
  • Cyclic Hydrocarbons
  • Diffusion Coefficient
  • Electrochemistry
  • Electrodes
  • Electron Transfer
  • Electrons
  • Fluids
  • High Pressure
  • High Temperature
  • Materials
  • Metals
  • New York
  • Transition Metals

Fields of Study

  • Chemistry

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Electrochemical Surface Science
  • Organic Chemistry

Technology Areas

  • Microelectronics