Synthesis of New Prophylactic Antiradiation Drugs.

Abstract

This report is divided into four (4) major sections. Each section addresses a phase of the syntheses of adamantyl aryl alkylamines where the amine is incorported into an N-substituted 2-mercaptoacetamidine, or a derivative of the sulfide function. The first part describes the efforts in the 1-aryl-3-adamantyl-methylamine series where the aryl group is 2-thienyl. The next section is devoted to the practical approaches to the synthesis of 1-aryl-2-adamantylalkyl-amines. The work culminates in the preparation of the first member, namely, 1-phenyl-2-adamantylmethylamine. The third section describes some preliminary work on the preparation of 1-aryl-4-adamantylalkylamines. And, the last section reports the synthesis of 4-(1-adamantyl)benzylamines and its conversion to the disulfide based on N-(4-(1-adamantyl)benzyl)-2-mercaptoacetamidine.

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Document Details

Document Type
Technical Report
Publication Date
Aug 01, 1983
Accession Number
ADA148649

Entities

People

  • L. Bauer

Organizations

  • University of Illinois Urbana–Champaign

Tags

Communities of Interest

  • Biomedical

DTIC Thesaurus Topics

  • Alcohols
  • Alkanes
  • Amines
  • Chemical Synthesis
  • Chemistry
  • Chlorides
  • Chromatography
  • Hydrogen
  • Hydroxides
  • Materials
  • Organic Chemistry
  • Sodium Compounds
  • Sodium Hydroxide
  • Sulfur Compounds

Fields of Study

  • Chemistry

Readers

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  • Organic Chemistry