Homogeneous Reaction Involving Components of Different Redox Couples. I. Theoretical Considerations and Digital Simulation.

Abstract

Coupled heterogeneous electron transfer/homogeneous reactions occur in the electro-oxidation of certain anilines, and in association reactions of hydrocarbon anions with metal cations. If the adduct A sub m sub R is electroinactive, the resulting voltammogram is distorted in a way which is characteristic of the value of m. The derivation of the theoretical fluxes for these reactions and calculated normal potential pulse voltammograms are presented. The results are derived from both limiting flux and digital simulation considerations. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Nov 28, 1984
Accession Number
ADA148666

Entities

People

  • J. Janata
  • J. K. Foley
  • S. B. Khoo
  • S. Feldberg
  • Stanley Pons

Organizations

  • University of Utah

Tags

Communities of Interest

  • Materials and Manufacturing Processes

DTIC Thesaurus Topics

  • Alkali Metals
  • Chemical Reactions
  • Chemistry
  • Coefficients
  • Differential Equations
  • Diffusion Coefficient
  • Electron Flux
  • Electron Transfer
  • Equations
  • Kinetics
  • Measurement
  • Military Research
  • New York
  • Oxidation
  • Partial Differential Equations
  • United States
  • Universities

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Electrochemical Surface Science
  • Radar Systems Engineering.

Technology Areas

  • Microelectronics
  • Microelectronics - Microelectromechanical Systems