Synthesis and Reactivity of (Bis(trimethylsilyl)Methylene)(Mesityl)Phosphine.
Abstract
Two recent papers have described the synthesis and characterization of a series of P-mesityl substituted phosphorus compounds containing Si-N-P and/or Si-C-P linkages. These systems are of interest, in part, as precursors to new types of low-coordinate phosphorus compounds including (methylene) phosphines, RP-CR2 double bond, and imino (methylene) phosphoranes, RP(-NR)-CR2 double bonds. As an extension of these studies, we report here the synthesis and some derivative reactions of bis(Trimethylsilyl)methylene(mesityl)phosphine.
Document Details
- Document Type
- Technical Report
- Publication Date
- Dec 12, 1984
- Accession Number
- ADA148803
Entities
People
- P. Wisian-neilson
- R. H. Neilson
- X. M. Xie
Organizations
- Texas Christian University