Characterization of Novel Binders Based on Energetic Thermoplastic Elastomers.

Abstract

Beginning in the fall of 1981, a research program was undertaken to develop a series of block copolymers based on novel polyethers. This research is part of the Low Vulnerability Ammunition, LOVA, program of the Office of Naval Research. The principal polymers of interest in this program are the crystalline polyBEMO and polyBAMO, and their thermoplastic elastomers. The most important findings of the past year are: PolyBEMO decomposes endothermally at elevated temperatures, meeting an important LOVA objective of safer compositions; The use temperatures of polyBEMO, polyBAMO, and their block copolymers range from -30 to +75 C. The modulus of the block copolymers is leathery to rubbery, depending on the composition; Processing can be carried out in the range of 80-110 C; and PolyBEMO and polyBAMO are highly crystalline materials. PolyBEMO exhibits more than one crystalline form. Major focus of the research has been to characterize the thermal and physical behavior of these materials.

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Document Details

Document Type
Technical Report
Publication Date
Sep 30, 1984
Accession Number
ADA148993

Entities

People

  • L. H. Sperling

Organizations

  • Lehigh University

Tags

Communities of Interest

  • Counter IED
  • Ground and Sea Platforms

DTIC Thesaurus Topics

  • Availability
  • Binders
  • Biomedical And Dental Materials
  • Block Copolymers
  • Chemical Engineering
  • Classification
  • Copolymers
  • Elastomers
  • Engineering
  • Mass Spectrometry
  • Materials
  • Military Research
  • Neutron Scattering
  • Phase Separation
  • Polymeric Films
  • Polymers
  • Security

Fields of Study

  • Materials science

Readers

  • Defense Technology Research and Development.
  • Polymer Science and Technology

Technology Areas

  • Microelectronics