Polymer Electrolytes: An Investigation of Some Poly (N-Propylaziridine)/Lithium Salt Compositions.

Abstract

Some poly(N-propylaziridine)/lithium salt compositions have been synthesized and their electrical conductivities have been measured in order to assess their suitability as electrolytes in safe, leakproof, high energy-density lithium batteries operating at ambient temperature. The effects on conductivity of temperature, and the nature and concentration of the salt have also been studied. The presence of the salts markedly improved the conductivity of the compositions over that of the undoped polymer but they were insufficiently conducting to be considered as battery electrolytes, due possibly to ion-pairing. Their creep resistance was also low. It was concluded that less fluid compositions containing higher molecular weight polymers better able to promote ion separation would be more suitable.

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Document Details

Document Type
Technical Report
Publication Date
Apr 01, 1984
Accession Number
ADA149444

Entities

People

  • A. J. Golder
  • Jessica H Knight
  • K. R. Baldwin

Organizations

  • Royal Aircraft Establishment

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Alkenes
  • Carbonate Esters
  • Chemistry
  • Electrical Conductivity
  • Energy
  • Films
  • Glass Transition Temperature
  • High Energy
  • Lithium Batteries
  • Magnetic Resonance
  • Materials
  • Mechanical Properties
  • Molecular Weight
  • Nuclear Magnetic Resonance
  • Perchlorates
  • Resistance
  • Transition Temperature

Fields of Study

  • Materials science

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Polymer Science and Engineering.