Carbon Vaporization/Condensation Effects

Abstract

The energy dissipating efficiency of carbon materials were studied. Equilibrium thermochemical properties and kinetic vaporization rate information have been obtained for temperatures approaching 4500 deg K. A nonequilibrium ablation model and carbon laser vaporization experiments were used to determine the total vapor pressure, melt temperature limits, and the temperature dependence of carbon vaporization (rate) coefficients for different types of graphite. In addition, rough surface emissivities for these graphites were measured, and a preliminary study of the effects of carbon particles on infrared radiation transport in a laser-vaporized carbon plume was carried out. This information makes possible the reliable prediction of the performance of the carbon material thermal protection systems in extreme heat transfer environments. The measured vapor pressures are two to three times higher than those given by the current JANAF tables, and the melt temperature limits are 300 to 600 deg K higher than current literature values. To our knowledge, our data represent the first reported temperature dependence of carbon vaporization coefficients.

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Document Details

Document Type
Technical Report
Publication Date
Jul 31, 1984
Accession Number
ADA149475

Entities

People

  • J. C. Coffer
  • J. M. Mcdonough
  • K. C. Herr
  • R. A. Klingberg
  • R. L. Baker

Organizations

  • The Aerospace Corporation

Tags

Communities of Interest

  • Air Platforms

DTIC Thesaurus Topics

  • Carbon Dioxide Lasers
  • Heat Energy
  • Heat Transfer
  • Laser Beams
  • Lasers
  • Materials
  • Materials Science
  • Measurement
  • Particle Size
  • Plastic Explosives
  • Radiative Transfer
  • Scattering
  • Spectra
  • Spectroscopy
  • Surface Temperature
  • Thermal Conductivity
  • Thermodynamic Properties

Readers

  • Combustion science or combustion engineering.
  • Thermal Physics or Thermal Science.

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers