Average Collisional Vibrational Energy Transfer Quantities and the Inversion Temperature.
Abstract
Collisional efficiencies for vibrational energy transfer have previously been related to certain quantities, which have been examined here as a function of molecular complexity, critical reaction threshold, E sub O temperature and energy transfer step size. Model calculations were made for the decomposition of nitryl chloride and for the isomerizations of methyl isocyanide, cyclopropane and cycloheptatriene. Additional keywords: high temperature; inversion temperature; surfaces; tin; vibrational relaxation.
Document Details
- Document Type
- Technical Report
- Publication Date
- Mar 15, 1985
- Accession Number
- ADA152674
Entities
People
- Benton Seymour Rabinovitch
- D. C. Tardy
Organizations
- University of Washington