Gas Phase Ion-Molecule Chemistry of Carbon, Nitrogen and Oxygen Compounds.
Abstract
The gas phase reaction of nitrogen, silicon, sulfur and phosphorous organic compounds with anions have been investigated using the flowing afterglow technique. Studies have been made which compare mechanisms by which first and second row elements react with anions. New methods for the generation of specific anions in the gas phase have been developed. A variety of new types of gas phase ions (PH2(-), R5Si(-), C3H2NO2(-), etc.) have been prepared and their chemical reactions studied. Originator supplied keywords include: Flowing afterglow; Selected in flow tube; Reactivity; Mechanism; Thermochemistry; Trimethyl phosphite; Silyl anions; Phosphide anion; Nitrite esters; Sulfur dioxide; Methaneimine; Aza allyl anion; Sulfides; and Electron affinity.
Document Details
- Document Type
- Technical Report
- Publication Date
- Jan 29, 1985
- Accession Number
- ADA152876
Entities
People
- C. H. Depuy
- V. M. Bierbaum
Organizations
- University of Colorado Boulder