The Conversion of Smaller Borane Fragments to Larger Structures. Systematics of Boron Hydride Reactions.
Abstract
The synthesis and reaction chemistry of B4H8 adducts of strong bases including trimethylphosphine, the boron framework expansion through the use of B2H4.2PMe3, the synthesis of polyboron cations including B3H6.2PMe3(*) and B4H7.2PMe3(+), and the coordinations chemistry of B2H4.2PMe3 are summarized. Described also are the synthesis of isomers of dichloroborylpentaborane(9), the reacion chemistry of B3H7PH3, anomalies in the reaction of B4H10 with bases, the deuteration of triborane adducts and the deprotonation of B5H9 with solid KOH.
Document Details
- Document Type
- Technical Report
- Publication Date
- Dec 31, 1984
- Accession Number
- ADA153443
Entities
People
- G. Kodama
- R. W. Parry
Organizations
- University of Utah