T-Butyldimethylsilyl Derivatives of Some Alkylphosphonic and Alkyl Methylphosphonic Acids. Part 1. Gas Chromatographic/Mass Spectrometric Studies,
Abstract
Electron impact mass spectra have been generated for t-butyldimethylsilyl derivatives of several alkyl methylphosphonic, alkylphosphonic and halogen-substituted alkylphosphonic acids. In all cases, fragmentation is limited to a few abundant ions indicating that improved quantitation of this class of compounds, essential for verification of chemical arms agreements, will be possible by gas chromatographic/mass spectrometric means using these derivatives. Some fragmentation mechanisms are suggested to account for the major ions of the spectra.
Document Details
- Document Type
- Technical Report
- Publication Date
- Jan 01, 1985
- Accession Number
- ADA155037
Entities
People
- J. G. Pagotto
- J. G. Purdon
- R. K. Miller
- T. L. Stewart
Organizations
- Defence Research and Development Canada