A Study of the Chemistry of Alkali Metals in the Upper Atmosphere

Abstract

The reactions of metallic species introduced into the atmosphere by meteor ablation may play a significant role in mesospheric and stratospheric chemistry. During this second year of a three year program to investigate these phenomena, we have completed measurements for the reactions of atomic sodium with ozone, and of NaO with ozone. Preliminary measurements of the rate constant for the reaction of NaO2 + HCl have been done, as well as an initial photodissociation cross section determination for NaCl at 193 nm. We have also begun to investigate the means by which neutral gas phase alkali species may be removed from the mesosphere and stratosphere. Originator supplied keywords include: reaction rates, atomic sodium, mesospheric chemistry, stratospheric chemistry, diffusion, sodium hydroxide, hydrochloric acid, ozone.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1985
Accession Number
ADA156349

Entities

People

  • C. E. Kolb
  • J. A. Silver

Organizations

  • Aerodyne Research

Tags

Communities of Interest

  • Energy and Power Technologies
  • Materials and Manufacturing Processes
  • Weapons Technologies

DTIC Thesaurus Topics

  • Air Force
  • Alkali Metals
  • Chemical Reaction Properties
  • Chemical Reactions
  • Chemistry
  • Combustion
  • Diffusion Coefficient
  • Dissociation
  • Energy Transfer
  • Ionization
  • Laser Induced Fluorescence
  • Lasers
  • Measurement
  • Molecules
  • Oxidation
  • Physical Chemistry
  • Recombination Reactions

Fields of Study

  • Environmental science

Readers

  • Analytical Chemistry
  • Combustion science or combustion engineering.
  • Space Exploration and Orbital Mechanics.

Technology Areas

  • Space