A System for the Continuous Generation of Phosphorous Aerosols from Red Phosphorus-Butyl Rubber. Chemical Characterization and Toxicological Evaluation of Airborne Mixtures

Abstract

A system for the continuous generation of phosphoric acid aerosols from burning Red Phosphorus-Butyl Rubber (RPBR) is described. The system is primarily intended for inahlation toxicology experiments using high aerosol concentrations (ca. 0.3 to 3 g/cu m), but is adaptable to other studies where a time independent concentration of the aerosol is desired in a flowing system. The RPBR formulation is softened by addition of a small amount of hexane and extruded at a controlled rate at high pressure through an orifice. A precision hydraulic extrusion system using a micrometer adjustable high pressure hydraulic pump has been developed to control the extrusion rate. The emerging filament is ignited and burned in a flowing air stram for delivery to chambers. In addition to the extrusion-combustion system for aerosol generation, devices for recovering the spent aerosol and for monitoring its concentration are described.

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Document Details

Document Type
Technical Report
Publication Date
May 01, 1984
Accession Number
ADA157342

Entities

People

  • J. H. Moneyhun
  • R. W. Holmberg
  • T. M. Gayle

Organizations

  • Oak Ridge National Laboratory

Tags

Communities of Interest

  • Biomedical
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Amplifiers
  • Butyl Rubber
  • Chemical Analysis
  • Chemistry
  • Combustion
  • Construction
  • Detectors
  • Flow Rate
  • High Pressure
  • Light Scattering
  • Materials
  • Materials Processing
  • Materials Science
  • Phosphoric Acids
  • United States
  • United States Government
  • Warning Systems

Fields of Study

  • Environmental science

Readers

  • Aerosol Science/Aerosol Physics
  • Combustion science or combustion engineering.
  • Toxicology/Environmental Toxicology