Analysis Technique for Determining the Levels of Organic Additives in an EPDM Rubber for Use in Underwater Acoustic Applications.

Abstract

Ethylene-propylene diener monomer (EPDM) rubber is being considered for applications in underwater electroacoustic transducers. This material is attractive for such applications because it is acoustically transparent over a wide range of frequencies with very low loss and has an excellent environmental resistance. An optimized Navy EPDM formulation for transducer applications has been developed at Underwater Sound Reference Detachment (USRD) under the support of the Office of Naval Research (ONR) Acoustic Transduction and Metrology Program. In order to ensure that the Navy receives materials as specified according to this EPDM formulation, analytical procedures for determining the various ingredients in EPDM rubber need to be developed for quality-control purposes. An analytical procedure for determining the organic additive levels in this EPDM formulation is given in this report. By using a liquid-solid chromatography (LSC) method, one can now measure reproducibly the percentages of dicumyl peroxide (DCP), trimethylolpropane trimethacrylate (TMPTMA), and polymerized 2,2,4-trimethyl-1,2-dihydroquinoline (TMDQ) in EPDM rubber. Chemical structures for these materials are shown. This procedure was tested by conducting a blind study on three compounded EPDM rubbers and was proven to be satisfactory.

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Document Details

Document Type
Technical Report
Publication Date
Aug 15, 1985
Accession Number
ADA159230

Entities

People

  • M. E. Quinn
  • W. W. Mcgee

Organizations

  • United States Naval Research Laboratory

Tags

DTIC Thesaurus Topics

  • Alcohols
  • Alkanes
  • Back Pressure
  • Chromatography
  • Cyclic Hydrocarbons
  • Cyclohexanes
  • Detectors
  • Elastomers
  • Electroacoustic Transducers
  • Flow Rate
  • Liquid Chromatography
  • Materials
  • Military Research
  • Quality Control
  • Rubber
  • Transducers
  • Underwater Sound

Fields of Study

  • Materials science

Readers

  • Analytical Chemistry
  • Polymer Science and Engineering.