Chemical Bonding, Interdiffusion and Electronic Structure at InP, GaAs, and Si-Metal Interfaces.

Abstract

An experimental program investigates the interface electronic states and band structure at Germanium Arsenides, Indium Phosphides and Silicon-metal interfaces formed by chemical reaction and interdiffusion at room temperature, elevated temperatures, as well as following pulsed-laser annealing; uses soft x-ray photoemission spectroscopy (SXPS) and Auger electron spectroscopy (AES)/depth profiling to characterize atomic redistribution and new chemical bonding near the surfaces and interfaces on an atomic scale; refines the technique of cathodoluminescence spectroscopy (CLS) for investigations of new compound and defect formation at buried metal-semiconductor interfaces; and employs temperature-dependent current-voltage and capacitance-voltage measurements to characterize the electronic properties and spatial distribution of interface states of metal-InP interfaces prepared and processed under carefully controlled conditions. The work can be grouped into four areas: 1) chemical and electronic structure of buried III-V and II-VI compound semiconductor-metal interfaces, 2) localized chemical reactions at Aluminum interfaces with III-V compound semiconductors promoted by pulsed-laser annealing as well as laser-induced oxidation of Si, 3) eletrical characterization of the UHV-prepared Al-InP (110) interface, and 4) control of competitive Ti-Si and Ti-SiO2 interfacial reactions by rapid thermal annealing.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Oct 01, 1985
Accession Number
ADA160403

Entities

People

  • L. J. Brillson

Organizations

  • Xerox

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Auger Electron Spectroscopy
  • Auger Electrons
  • Band Structures
  • Chemical Reactions
  • Chemistry
  • Compound Semiconductors
  • Electrical Properties
  • Electron Spectroscopy
  • Electronics Industry
  • Energy Bands
  • Laser Beams
  • Measurement
  • Optical Properties
  • Semiconductor Devices
  • Semiconductors
  • Spectra
  • Thermal Conductivity

Fields of Study

  • Materials science

Readers

  • Semiconductor Device Technology
  • Thin Film Deposition Science.

Technology Areas

  • Directed Energy
  • Directed Energy - Pulsed-Laser Deposition
  • Microelectronics
  • Microelectronics - Graphene