Development of a Test Method to Determine Potential Peroxide Content in Turbine Fuels.

Abstract

A test method was developed for the prediction of peroxide potential of fuels, experimental conditions were sought so that the oxidative tendencies of fuels could be assessed within a reasonable time i.e., less than 48 hours. Through the generally accepted 43 C (110 F) bottle storage method fo accelerated fuel aging, the relative ratings of four selected fuels' oxidative tendencies were established. A matrix of experiments was designed to allow selection of those short-term reaction conditions that would give results comparable to the 43 C bottle storage experiments. Additionally, the results of these experiments would allow the development of global reaction kinetics to aid the determination of fuel peroxidation potential. From a partially completed experimental matrix, fuel stressing was completed at 60 and 100 C under an initial oxygen pressure of 689 kPa (100 psig). Experimental results at 60 C gave inconclusive results. Results of the 100 C experiments produced essentially self-consistent results that also agreed with those of the bottle storage for the most stables and least stable fuels. Results of the two intermediate stability fuels, however were interchanged.

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Document Details

Document Type
Technical Report
Publication Date
Jun 01, 1985
Accession Number
ADA163590

Entities

People

  • D. W. Naegeli
  • G. E. Fodor
  • J. P. Cuellar Jr.
  • K. B. Kohl

Organizations

  • Southwest Research Institute

Tags

Communities of Interest

  • Air Platforms
  • Ground and Sea Platforms
  • Space
  • Weapons Technologies

DTIC Thesaurus Topics

  • Abstracts
  • Air Force
  • Air Force Facilities
  • Chemical Kinetics
  • Chemistry
  • Classification
  • Engineering
  • Kinetics
  • Liquid Phases
  • Materials
  • Military Research
  • Munitions
  • Oxygen
  • Peroxides
  • Research Facilities
  • Security
  • Test Methods

Readers

  • Internal Combustion Engine (ICE) Technology.
  • Organic Chemistry
  • Systems Analysis and Design