Total Inversion on the Bi(62D-64S) Transition at 8758 A by Near-Resonant Collision Transfer with NF(a1 Delta).

Abstract

Total population inversion betwen the two lowest electronic states of atomic bismuth, (6 superscript 2D) and (6 superscript 4S), has been demonstrated in a subsonic flow system. The atomic inversion is generated via collisions of the ground state Bi (6 superscript 4S) with electronically excited NF(a superscript 1 delta)) in the extremely fast resonant transfer process. This result proves unequivocally that the NF(a superscript 1 delta), produced by the reaction H + NF2 yields HF(v) + NF(a superscript 1 delta) is also totally inverted. Keywords: Atomic and molecular physics; Chemical kinetics; Chemical lasers; Chemically reactive flows; Energy distribution and transfer; Flow tubes; NF chemical kinetics; NF molecules; Physical chemistry; Rate constants.

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Document Details

Document Type
Technical Report
Publication Date
Feb 28, 1986
Accession Number
ADA166358

Entities

People

  • John M. Herbelin
  • Robert A. Klingberg

Organizations

  • The Aerospace Corporation

Tags

Communities of Interest

  • Materials and Manufacturing Processes
  • Space

DTIC Thesaurus Topics

  • Air Force
  • Atoms
  • Chemical Kinetics
  • Chemical Reactions
  • Chemistry
  • Construction
  • Corporations
  • Emission
  • Emission Spectra
  • Flow
  • Flow Rate
  • Ground State
  • Inversion
  • Physical Chemistry
  • Security
  • Spectra
  • Two Dimensional

Fields of Study

  • Physics

Readers

  • Combustion science or combustion engineering.
  • Neurological Diseases/Conditions/Disorders
  • Quantum spin resonance or Electron Paramagnetic Resonance spectroscopy.

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers
  • Microelectronics
  • Microelectronics - Graphene