Important Experimental Parameters for the Nitrogen Dioxide Permeation Testing of the Propellant Handler's Ensemble Coverall Material

Abstract

We reviewed a NASA and an Air Force permeation test procedure and found them to be inadequate for their intended purpose of being standards for inter-laboratory comparison of the permeation resistance of material samples. In order to evaluate the importance of the various experimental parameters that were neither defined nor controlled by these earlier test specifications, we developed a new permeation test apparatus and procedure and applied them to the evaluation of the experimental parameters and several coverall materials. In this report we describe a test apparatus and detailed procedure for carrying out reproducible conditioning of material samples by controlled exposure to known volumes of liquid hypergols at a well-defined temperature as well as subsequent quantitative permeation testing of the conditioned samples under conditions of controlled temperature, absolute pressure, differential pressure, and equivalent concentration of dinitrogen tetroxide vapor (N204). We applied this apparatus to the nitrogen dioxide (NO2) permeation testing of three materials: the E.I. du Pont de Nemours chlorobutyl material currently used in the construction of the rocket fuel handler's clothing outfit (RFHCO) the du Pont cholorobutyl material proposed for use in the Propellant Handler's Ensemble (PHE), and the ILC Dover chlorinated polyethylene material currently used in the Chemturion (CHEM) protective ensemble. Both the RFHCO and PHE coverall materials resisted No2 permeation for more than 60 min under all test conditions that were investigated.

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Document Details

Document Type
Technical Report
Publication Date
Apr 07, 1986
Accession Number
ADA166719

Entities

People

  • Robert N. Abernathy

Organizations

  • The Aerospace Corporation

Tags

Communities of Interest

  • Space
  • Weapons Technologies

DTIC Thesaurus Topics

  • Air Force
  • Chemical Kinetics
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Control Systems
  • Detection
  • Materials
  • Materials Science
  • Materials Testing
  • Nitrogen Oxides
  • Partial Pressure
  • Physics Laboratories
  • Polymeric Films
  • Rocket Oxidizers
  • Test And Evaluation
  • Vapor Pressure

Readers

  • Combustion science or combustion engineering.
  • Materials Science
  • Polymer Science and Engineering.