Measurement of Rate Constants of Elementary Gas-Reactions of Importance to Upper Atmosphere and Combustion Systems.

Abstract

This report discusses the Air Force's enhanced flow reactor. The major items purchased were a bakeable, differentially pumped, UHV envelope to interface the mass spectrometer to the flow tube and an excimer pumped dye laser system for laser excited fluorescence (LEF) detection of radicals in the flow tube. The LEF system, employing a Lambda Physik excimer pumped dye laser (EMG 103 MSC/FL 2001), has been operational since mid-autumn. It has already been used in preliminary studies of our new methoxy radical source. Completion of the mass spectrometer system was delayed by a variety of problems. However, by late October the required parts were on hand, and the vacuum envelope, sans mass spectrometer, was successfully pumped down. The complete system is currently assembled adn undergoing final testing reactions. Keywords: Hydroxylradical, and Chemical reactions.

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Document Details

Document Type
Technical Report
Publication Date
Feb 24, 1986
Accession Number
ADA167177

Entities

People

  • Frederick Kaufman

Organizations

  • University of Pittsburgh

Tags

Communities of Interest

  • Counter IED
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Acquisition
  • Atmospheres
  • Chemical Reactions
  • Classification
  • Combustion
  • Corporations
  • Dye Lasers
  • Gases
  • Generators
  • Joints
  • Laser Beams
  • Lasers
  • Liquid Dye Lasers
  • Mass Spectrometers
  • Measurement
  • O Rings
  • Stainless Steel

Fields of Study

  • Physics

Readers

  • Chemistry (specifically Chemical Fluorescence)
  • Combustion and Flow Dynamics.
  • Pulsed Power and Plasma Physics.

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers