An Interdisciplinary Approach to Predictive Modeling of Structural Adhesive Bonding. Characterization of Ti-6Al-4V Oxides and the Adhesive/Oxide Interphase.

Abstract

Ti-6-4, being a high strength, lightweight, corrosion resistant alloy, possesses many uses for structural adhesive bonding. Many researchers are therefore finding better pretreatments, characterizing the oxide surface and evaluating bonding performance. The work reported here will encompass both oxide characterization and evaluation of adhesive bonds. The chemical composition of oxides created by specific pretreatments was studied by XPS, AES, SIMS, contact angles, and indicator dyes. The surface topography and structure was probed by SEM, STEM, and profilometry. Following the procedures of Carre and Schultz with aluminum substrates, values for the surface energy of the Ti-6-4 oxides are obtained using an interfacial contact angle method. Because of the present interest in the use of Ti-6-4 for high temperature applications, the thermal stability of the oxide layer was investigated. Following Pike's successful use of inorganic primers as adhesion promoters on aluminum substrates, studies were begun to characterize a titanate primer. Finally, both lap shear and wedge tests have been used to evaluate the adhesive/oxide interphase.

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Document Details

Document Type
Technical Report
Publication Date
May 01, 1986
Accession Number
ADA170484

Entities

People

  • J. A. Filbey
  • J. P. Wightman

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Acids
  • Adhesive Bonding
  • Adhesives
  • Alkanes
  • Auger Electron Spectroscopy
  • Auger Electrons
  • Chemical Composition
  • Chemistry
  • Electron Microscopes
  • Electron Microscopy
  • Indicator Dyes
  • Mass Spectrometry
  • Measurement
  • Microscopes
  • Spectra
  • Spectrometry
  • Spectroscopy

Fields of Study

  • Materials science

Readers

  • Structural Health Monitoring of Composite Structures.
  • Thin Film Deposition Science.