Corrosion Fatigue and Electrochemical Reactions in Modified HY130 Steel.

Abstract

To investigate the relationship between corrosion fatigue crack growth response of high strength steels in aqueous environments and electrochemical reactions at the crack tip, fatigue and electrochemical simulation tests were carried out on a modified HY-130 steel in acetate buffer solution. Corrosion fatigue crack growth rate were determined as a function of temperature (276 to 363 K) and frequency (0.03 to 10 Hz) under open circuit conditions. The electrochemical simulation experiments were carried out over the same range of temperatures, and measured the galvanic current transient between a clean and an oxidized surface and the corresponding mixed potential. These experiments were based on the assumption that the newly created surfaces at the crack tip and its neighboring oxidized surfaces formed a localized galvanic cell. Results from the two sets of experiments strongly suggested electrochemical reaction control of corrosion fatigue crack growth. The electrochemical experiments indicated that hydrogen evolution in this system followed the Volmer-Heyrovsky mechanism. Keywords: Environmental effects; Electrochemistry; Fracture mechanics.

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Document Details

Document Type
Technical Report
Publication Date
May 01, 1986
Accession Number
ADA172242

Entities

People

  • Gunchoo Shim
  • Robert P. Wei

Organizations

  • Lehigh University

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Cells
  • Chemical Kinetics
  • Chemistry
  • Electrochemical Cells
  • Electrochemical Reactions
  • Electrodes
  • Engineering
  • Fatigue Tests (Mechanics)
  • Hydrogen Embrittlement
  • Materials
  • Materials Science
  • Mechanics
  • Military Research
  • Photoelectrochemical Cells
  • Regression Analysis
  • Steady State
  • United States

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Thin Film Deposition Science.