Electrochemistry of Sulfur, Na2S, S2, S2Cl2 and CS2 in 1-Methyl-3-Ethylimidazolium Chloride-Aluminum Chloride Melts.

Abstract

The electrochemical behavior of sulfur, sodium sulfide, sulfur monochloride and carbon disulfide was studied on a glassy carbon electrode at 25 C in 1-methyl-3-ethylimidazolium chloroaluminate melts in basic (excess organic chloride), neutral (1:1 mole ratio of organic chloride and AlCl 3) regions. Cyclic voltammetry, rotating disk electrode and steady-state potentiostatic techniques were used in the study. The literature on sulfur and sulfur compounds in NaCl-AlCl3 melts is reviewed and comparisons are made with the room temperature melts.

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Document Details

Document Type
Technical Report
Publication Date
Aug 01, 1986
Accession Number
ADA172401

Entities

People

  • B. J. Piersma
  • J. S. Wilkes

Organizations

  • Air Force Research Laboratory

Tags

Communities of Interest

  • Cyber
  • Materials and Manufacturing Processes
  • Weapons Technologies

DTIC Thesaurus Topics

  • Air Force
  • Aluminum
  • Chlorides
  • Contracts
  • Department Of Defense
  • Electrochemistry
  • Electrodes
  • Elements
  • Foreign Languages
  • Government Procurement
  • Governments
  • Language
  • Plastic Explosives
  • Standards
  • Steady State
  • Sulfur Compounds
  • United States

Fields of Study

  • Chemistry

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies