Silylated Phosphines and Phosphoranimines.

Abstract

The N-silylphosphoranimines E.G., Me3/SiN=P (OCH2CF3)Me2 undergo a variety of reactions including deprotonation/substitution of the P-Me groups, transilylation, and condensation with reactive phosphines. Some new 1,2-addition and oxidation reactions of the P=C systems, R2NP=CHR, R2NP(=NR)=CHR, and R2NP=CR-CH=CHR )R = SiMe3) are also reported. Keywords: methylenephosphine.

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Document Details

Document Type
Technical Report
Publication Date
Oct 10, 1986
Accession Number
ADA173455

Entities

People

  • Bruce A. Boyd
  • Donn A. Dubois
  • Gary M. Scheide
  • Rahim Hani
  • Robert H. Neilson

Organizations

  • Texas Christian University

Tags

Communities of Interest

  • Materials and Manufacturing Processes

DTIC Thesaurus Topics

  • Abstracts
  • Chemical Reactions
  • Chemistry
  • Christianity
  • Classification
  • Condensation
  • Governments
  • Military Research
  • Organophosphorus Compounds
  • Oxidation
  • Phosphine
  • Procurement
  • Security
  • United States
  • United States Government
  • Universities

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Polymer Science and Technology