Alpha-Methylstyrl- and Styrlphosphazene Monomers and Polymers.
Abstract
The synthesis of the m and p alpha-methylstyrl-phosphazenes, N3P3F6-n (C6H4C(CH3)=CH2)n (n=1,2) is reported. Aqt the bis stage of substitution, all isomers are observed with the cis non-geminal species predomination. The mono alpha-methylstyrl derivatives enter into facile copolymerization reactions wherein both terminal and pennultimate mechanisms are observed. The synthesis and homopolymerization of styrlpentafluorocyclotriphosphazene is discussed.
Document Details
- Document Type
- Technical Report
- Publication Date
- Oct 03, 1986
- Accession Number
- ADA173702
Entities
People
- Christopher W. Allen
- Jonathan C. Shaw
Organizations
- University of Vermont