Polydioxolane Polymer Electrolyte.

Abstract

Polymer electrolytes formed by the chemical and electrochemical polymerizatiof a solution of LiAsF6 in dioxolane have been examined. The liquid electrolyte has been stabilized by preparing and storing it in the presence of Li metal as a proton and carbocation scavenger. The initial results show that the polymerization of the electrolyte is readily initiated chemically by acids or oxidizing agents. The polymerization continues so that the conductivity of the resulting polymer electrolyte decreases over 24 hrs at room temperature approaching .000001 S/cm.

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Document Details

Document Type
Technical Report
Publication Date
Oct 18, 1986
Accession Number
ADA174092

Entities

People

  • J. S. Foos
  • S. M. Erker

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Abstracts
  • Chemical Compounds
  • Chemical Engineering
  • Chemistry
  • Electrolytes
  • Engineering
  • Engineers
  • Ionic Liquids
  • Jet Propulsion
  • Liquids
  • Materials
  • Materials Science
  • Military Research
  • New Jersey
  • New York
  • Polymerization
  • Polymers

Fields of Study

  • Materials science

Readers

  • Organic Chemistry
  • Polymer Science and Technology
  • Surface Engineering/Surface Coating Technology.