Optimization of the Finnigan MAT 5100 Capillary Gas Chromatograph-Mass Spectrometer for the Analysis of Polychlorinated Biphenyls.

Abstract

The basis of operation of a capillary gas chromatograph with a quadrupole mass spectrometer as a detector is reviewed. This is followed by the description of the optimization of a Finnigan MAT 5100 gas chromatograph-mass spectrometer-data system (GC/MS/DS) for the detection and identification of PCBs. In particular, the effects of increasing electron multiplier voltage and the use of multiple ion detection (MID) scan sequences on the sensitivity of the quadrupole mass spectrometer are investigated. Both increasing the electron multiplier voltage and the use of specialized MID scan sequences were found to result in an improved detector response.

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Document Details

Document Type
Technical Report
Publication Date
Nov 01, 1986
Accession Number
ADA176013

Entities

People

  • J. A. Hiltz
  • J. J. Power

Organizations

  • Defence Research and Development Canada

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Abstracts
  • Analyzers
  • Biphenyl
  • Chemical Compounds
  • Chromatographs
  • Detection
  • Detectors
  • Electron Multipliers
  • Electrons
  • Frequency
  • Identification
  • Mass Spectra
  • Mass Spectrometers
  • Mass Spectrometry
  • Polychlorinated Biphenyls
  • Security
  • Spectrometers

Readers

  • Aquatic Ecology
  • Solar Physics
  • Systems Analysis and Design

Technology Areas

  • Microelectronics