Protective Oxides Formed on CoCrAlY Coatings.

Abstract

The metallic coatings used to protect the hot-section turbine blades of marine gas turbines are often a mixture of cobalt, chromium, aluminum, and yttrium (CoCrA1Y). Using the surface sensitive technique of x-ray photoelectron spectroscopy, the protective oxide scales on CoCrA1Y coatings containing nominal levels of 20, 29, and 35wt% chromium were found to be essentially the same and were predominantely alumina and a yttrium rich phase that is tentatively identified as yttrium aluminum garnet. As increasing levels of chromium in this coating system are known to improve the coating's hot corrosion resistance, the similarity of the initial scales on all these coatings leads to the conclusion that chromium provides its hot corrosion benefit by slowing the propagation phase of the bulk coating attack.

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Document Details

Document Type
Technical Report
Publication Date
Nov 01, 1986
Accession Number
ADA176137

Entities

People

  • David W Taylor
  • Louis F. Aprigliano

Tags

Communities of Interest

  • Advanced Electronics
  • Ground and Sea Platforms

DTIC Thesaurus Topics

  • Aluminum Oxides
  • Corrosion Resistance
  • Electrons
  • Elements
  • Emission
  • Energy
  • Kinetic Energy
  • Materials
  • Physical Vapor Deposition
  • Resistance
  • Spectra
  • Spectroscopy
  • Sputtering
  • Turbines
  • X Ray Photoelectron Spectroscopy
  • X Rays
  • Yttrium Aluminum Garnet

Fields of Study

  • Materials science
  • Physics

Readers

  • Atmospheric Science / Meteorology, specifically Wind Wave Turbulence.
  • Materials Science and Engineering.
  • Surface Engineering/Surface Coating Technology.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene