Photoelectrochemical Cells Based on Inhomogeneous Semiconductor Electrodes.

Abstract

A dead-layer model based on PL intensity can be applied to two families of inhomogeneous electrodes used in PEC's: isotype heterojunctions and strained-layer superlattices. The dead-layer model assumes that electron-hole pairs formed within a distance on the order of the depletion width do not recombine. This mode was used to map the electric field in the aforementioned inhomogeneous electrodes. The dead-layer model can be refined to yield absolute depletion widths and surface recombination velocities of n-GaAs semiconducting electrodes in PEC's employing aqueous telluride electrolyte. The simple dead-layer model has also been used successfully on semiconductors whose surfaces have been modified for chemical reactivity.

Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1986
Accession Number
ADA176504

Entities

People

  • Arthur B. Ellis

Tags

DTIC Thesaurus Topics

  • Cells
  • Chemical Compounds
  • Compound Semiconductors
  • Electric Fields
  • Electrodes
  • Electrolytes
  • Electron Holes
  • Electronics
  • Electrons
  • Heterojunctions
  • Intensity
  • Photoelectrochemical Cells
  • Reactivities
  • Semiconductors
  • Solid State Electronics
  • Superlattices

Fields of Study

  • Materials science

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Plasma Physics / Magnetohydrodynamics
  • Semiconductor Device Technology

Technology Areas

  • Microelectronics