Rapid Thermal Oxidation and Nitridation of Silicon,

Abstract

Rapid thermal processing of silicon in oxygen and ammonia reactive ambients was employed to grow thin layers of Silicon dixoide, silicon nitride and nitroxide for high-quality gate insulators of submicron CMOS VLSI. Rapid thermal oxidation of (100) silicon in dry oxygen exhibited a nonlinear growth in the short-time regime. The oxide-growth rate rises as the oxidation time is reduced, and the highest rate occurs for the shortest rapid oxidation time. The formation kinetics of the surface and interface nitrogen-rich layers in rapidly nitrided oxide dielectrics were analyzed and correlated to their electrical performance. Rapid thermal nitridation of approx. 100 A SiO2 on silicon results in a negative shift of flatband voltage, a slight rise in surface-state density, a higher low-field and a lower high field conductivity, an improvement in the dielectric breakdown field, modified trapping characteristics, and a slower generation rate of new surfce states by the high-field electrical stress.

Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1986
Accession Number
ADA177295

Entities

People

  • Krishna C. Saraswat
  • Mehrdad M. Moslehi
  • Steven C. Shatas

Organizations

  • Stanford University

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Advanced Materials
  • Biomedical And Dental Materials
  • Ceramic Materials
  • Chemical Compounds
  • Chemistry
  • Conductivity
  • Demographic Cohorts
  • Dielectrics
  • Kinetics
  • Materials
  • Materials Science
  • Nitrogen
  • Nitrogen Compounds
  • Oxidation
  • Oxides

Fields of Study

  • Materials science

Readers

  • Atmospheric Science / Meteorology, specifically Wind Wave Turbulence.
  • Semiconductor Device Technology
  • Thin Film Deposition Science.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene