Synthesis and Characterization of a Dimeric Tris(Arsino)Gallane Containing a Nonplanar (Ga-As)2 Ring: Crystal Structure of ((Me3SiCH2)2As)3Ga)2.
Abstract
The dimer Methyl Silica Arsino gallane, only the second tris (arsino) gallane to be completely characterized, has been prepared from the reaction of Methyl Silica lithium arside with Gallium Chloride; X-ray crystallographic analysis shows it to be the first example of a compound containing a distinctly nonplanar four-membered ring of alternating four-coordinate Ga and As atoms.
Document Details
- Document Type
- Technical Report
- Publication Date
- Feb 11, 1987
- Accession Number
- ADA177304
Entities
People
- Andrew P Purdy
- Andrew T. McPhail
- Colin G. Pitt
- Kelvin. T. Higa
- Richard L. Wells
Organizations
- Duke University