Chemical and Enzymatic Triggering of 1,2-Dioxetanes.2. Fluoride-Induced Chemiluminescence from tert-Butyldimethylsilyloxy-Substituted Dioxetanes.
Abstract
Thermally stable 1,2-dioxetanes bearing tert-butyldimethylsilyloxyaryl groups have been prepared. Reaction of these dioxetanes with fluoride ion at ambient temperature in Methyl cyanate and DMSO generates chemiluminescence with efficiencies up to 25%. Keywords: Chemiluminescence; Oxetanes; High Efficiency; 1,2-Dioxetanes, Fluoride triggering; Photooxygenation.
Document Details
- Document Type
- Technical Report
- Publication Date
- Mar 17, 1987
- Accession Number
- ADA178500
Entities
People
- A. P. Schaap
- Briji P. Giri
- Renuka Desilva
- Richard S. Handley
- Tsae-shyan Chen
Organizations
- Wayne State University