Kinetics of Charge Transfer at Metal Electrolyte Interfaces: From Classical to Quantum Statistics.

Abstract

A survey of recent developments in the theory and experimental knowledge of the charge interfaces are discussed in relation to the problem of electron transfer reactions. An attempt is made to reformulate the role of the solvent in bulk phase and at surfaces. Furthermore we discuss the effect of position dependent tunneling on the reaction rate constant assuming simple distribution of the ions near the metallic interface. Keywords: Kinetics; Charge transfer statistical theory.

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Document Details

Document Type
Technical Report
Publication Date
May 12, 1987
Accession Number
ADA181010

Entities

People

  • Lesser Blum
  • M. Quijada
  • P. P. Schmidt

Organizations

  • University of Puerto Rico

Tags

Communities of Interest

  • Materials and Manufacturing Processes

DTIC Thesaurus Topics

  • Charge Transfer
  • Chemical Reactions
  • Chemistry
  • Density Functional Theory
  • Electrochemical Reactions
  • Electrodes
  • Electrolytes
  • Electron Transfer
  • Equations
  • Kinetics
  • Physics
  • Puerto Rico
  • Quantum Chemistry
  • Quantum Statistical Mechanics
  • Statistics
  • Transitions
  • United States

Fields of Study

  • Physics

Readers

  • Electrochemical Surface Science
  • Theoretical Analysis.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene
  • Quantum Computing