EPR (Electron Paramagnetic Resonance) Studies of Defects and Impurities in Boron-Implanted Hg sub 1-x Cd sub x Te.

Abstract

Representative high-purity single crystals of Hg(1-x) Cd(x) Te have been examined by electron paramagnetic resonance (EPR) to determine whether they contain Fe+3 impurities or defects. EPR spectra consistent with substitutional Fe+3 impurities were obtained from some CdTe samples, but no paramagnetic centers have been observed in p-type Hg0.7Cd0.3Te. Since boron ion-implanation is commonly used to produce n-p junctions in HgCdTe during the fabrication of infrared sensor devices, paramagnetic damage centers are likely to form but have not been previously demonstrated. We report the observation of free-electron -like EPR signals in heavily 11B+ implanted CdTe and Hg0.7Cd0.3Te. These spectra have similar EPR characteristics to the so-called dangling-bond defects generated in ion-implanted Si and GaP. Although the identities of these defects in HgCdTe remain to be established, the effects of implant conditions and thermal treatments are briefly described. Keywords: Mercury cadmium tellurids, Ion implantation damage, Defects in semiconductors, Electron paramagnetic, Resonance.

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Document Details

Document Type
Technical Report
Publication Date
May 22, 1987
Accession Number
ADA182436

Entities

People

  • E. L. Venturini
  • Robert C. Bowman Jr.

Organizations

  • The Aerospace Corporation

Tags

Communities of Interest

  • Advanced Electronics
  • Sensors
  • Space

DTIC Thesaurus Topics

  • Air Force
  • Classification
  • Compound Semiconductors
  • Electrons
  • Free Electrons
  • Implantation
  • Infrared Detectors
  • Ion Implantation
  • Ions
  • Magnetic Fields
  • Measurement
  • Quantum Numbers
  • Quantum Properties
  • Security
  • Semiconductors
  • Spectra
  • Spectrometers

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Semiconductor Device Technology

Technology Areas

  • Microelectronics