Chemisorption and Reactions of Molecules on Semiconductor Surfaces.

Abstract

We have performed experimental measurements of adsorbed atoms and molecules on metal and semiconductor surfaces over a wide range of temperatures (20K - 100K) to identify the nature of bonding, the structure, reaction intermediates and reaction products. This has included simple hydrocarbon and organic molecules on Ni, Pd, Pt and Ag single-crystal surfaces. The techniques of UV photoemission, low energy electron diffraction and high resolution electron energy loss spectroscopy were used and further developed to extract new information. The electronically excited states of absorbates relevant to Surface Enhanced Raman and Surface Chemistry were also investigated. Later work on Si(111) surfaces included studies of oxidation, water adsorption and metallization.

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Document Details

Document Type
Technical Report
Publication Date
May 18, 1987
Accession Number
ADA183059

Entities

People

  • J. E. Demuth

Organizations

  • IBM Thomas J. Watson Research Center

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Alkenes
  • Alkynes
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Desorption
  • Diffraction
  • Electron Energy
  • Electron Scattering
  • Electrons
  • High Resolution
  • Hydrocarbons
  • Measurement
  • Organic Chemistry
  • Scattering
  • Semiconductors
  • Surface Plasmons

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Quantum Chemistry
  • Thin Film Deposition Science.

Technology Areas

  • Microelectronics