Thin Metallic Films from Solvated Metal Atoms.

Abstract

Metals were evaporated under vacuum and the metal atoms solvated by excess organic solvents at low temperature. Upon warming stable colloidal metal particles were formed by controlled metal atom clustering. The particles were stabilized toward flocculation by solvation and electrostatic effects. Upon solvent removal the colloidal particles grew to form thin films that were metallic in appearance, bu showed higher resistivities than pure metallic films. Gold, palladium, and especially indium are discussed. Keywords: Indium, palladium, thin films, colloidal metal particles, free atoms, solvated, indium oxide films, clustering, electrophoresis, living colloids, non-aqueous solutions.

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Document Details

Document Type
Technical Report
Publication Date
Jul 14, 1987
Accession Number
ADA183529

Entities

People

  • Brock Dale
  • Galo Cardenas-trivino
  • Kenneth J. Klabunde

Organizations

  • Kansas State University

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Electron Microscopes
  • Electron Microscopy
  • Electrophoresis
  • Films
  • Low Temperature
  • Materials
  • Materials Laboratories
  • Materials Science
  • Microscopes
  • Oxide Films
  • Particle Size
  • Spectra
  • Thin Films
  • Vapors

Readers

  • Materials Science and Engineering.
  • Nanocomposite Materials Science
  • Quantum Chemistry