Stabilization of Z-RNA under Physiological Conditions and Recognition by Anti-Z DNA Antibodies.

Abstract

Radioimmunoassay and nitrocellulose filter-binding competition experiments were performed to determine the extent of recognition of Bromine-poly(r(C-G) by anti-Z-DNA antibodies. The polyclonal rabbit anti-Br-poly(d(C-G)igG preparations T4 and Z6 specifically recognize the Z-form of polyR(C-G, although the binding affinities are 10-to 100fold lower for Z-RNA than for various forms of Z-DNA. Competition RIA experiments verify the presence of a Z-DNA like determinant in left handed Br poly R(C-G) at physiological Sodium Chloride concentration. Phosphate buffer or high ionic strength conditions inhibit recognition of Z-RNA by anti Z-DNA IgGs, consistent with recognition of a phosphodiester backbone determinant. In summary, these spectroscopic and immunochemical studies demonstrate that under conditions of conformational stress (i.e. containing brominated nucleosides) left-handed Z-RNA is stable and is specifically recognized by proteins at physiological temperature and ionic strength.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1987
Accession Number
ADA184366

Entities

People

  • Charles C. Hardin
  • David A. Zarling
  • Joseph D. Puglisi
  • Mark O. Trulson
  • Peter W. Davis

Organizations

  • University of California

Tags

DTIC Thesaurus Topics

  • Biochemistry
  • California
  • Chemical Shifts
  • Chemical Synthesis
  • Chemistry
  • Copolymers
  • Crystal Structure
  • Identification
  • Magnetic Resonance
  • Military Research
  • Nuclear Magnetic Resonance
  • Raman Scattering
  • Raman Spectra
  • Recognition
  • Resonance
  • Scattering
  • Spectroscopy

Fields of Study

  • Biology

Readers

  • Molecular and Cellular Biochemistry