High-Resolution Absorption Spectroscopy of NO2

Abstract

The absorption cross section of NO2 has been measured above the 3979 predissociation limit in the region of 3920 and 3950, as well as in the discretely structured areas, around 4112 adn 4140. Spectra were taken in a dual- beam arrangement by means of a tunable, pulsed dye laser having a 0.05 bandwidth (FWHM). This represents an improvement of at least a factor of three over the resolution employed in previous studies. Below 3979 the spectra are continuous, with occasional diffuse rotational lines superimposed. The spectra taken above 4100 reveal a wealth of structural complexity. We report here absolute cross sections taken at 300K. The work above 4100 was also performed at 250K. Only slight variations in the measured cross sections are observed between these two temperatures.

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Document Details

Document Type
Technical Report
Publication Date
Aug 31, 1987
Accession Number
ADA184835

Entities

People

  • John B. Koffend
  • John S. Holloway
  • Munson A. Kwok
  • Raymond F. Heidner Iii

Organizations

  • The Aerospace Corporation

Tags

Communities of Interest

  • Advanced Electronics
  • Sensors
  • Space

DTIC Thesaurus Topics

  • Absorption
  • Absorption Spectra
  • Chemical Kinetics
  • Chemical Reactions
  • Chemistry
  • Detectors
  • Dye Lasers
  • High Resolution
  • Laser Spectroscopy
  • Liquid Dye Lasers
  • Materials
  • Materials Science
  • Measurement
  • Physics Laboratories
  • Semiconductor Devices
  • Spectra
  • Spectroscopy

Fields of Study

  • Physics

Readers

  • Molecular Photonics/Laser Physics
  • Optical Physics and Photonics.
  • Systems Analysis and Design

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers