Pyrazole Derivatives of Diborane(4).

Abstract

The present study was based on the assumption that a neutral Boron Pyrazole species would likely exist in a polymeric structure. Therefore, it should contain the bridging Boron Pyrazole units typical for pyrazaboles but also terminal B bonded Pyrazole groups and thus would be related to B-poly(1-pyrazolyl)pyrazaboles. Furthermore, a (pz)3B-B(pz)3 ion should be similar to a RB(pz)3 ion but for the fact that the former has two polydentate sites. These possibilities should provide for interesting variations as compared to the chemistry of B-(1-pyrazolyl)pyrazaboles and poly(1-pyrazolyl)borates, respectively. Keywords: tetrakis(1-pyrazolyl)dibor ane(4), (monomer, oligomers), bis(pyrazole)-tetrakis(1-pyrazolyl)diborane(4), hexakis(1-pyrazolyl)diborane(4) ate complexes.

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Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1987
Accession Number
ADA186277

Entities

People

  • C. P. Brock
  • Kurt S. Niedenzu
  • M. K. Das
  • R. P. Minton

Organizations

  • University of Kentucky

Tags

DTIC Thesaurus Topics

  • Alkanes
  • Chemical Synthesis
  • Chemistry
  • Chlorides
  • Crystal Structure
  • Crystals
  • Diffraction
  • Low Temperature
  • Materials
  • Metals
  • Military Research
  • Palladium
  • Pyrazoles
  • Spectra
  • Transition Metals
  • X Rays
  • X-Ray Diffraction

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Systems Analysis and Design