Molecular Motion and Energy Migration in Polymers.

Abstract

The first part of this report is concerned with research the aim of which is to establish whether or not electronic energy migration in synthetic polymers with pendant aromatic chromophores is a facile process or not. This is an area of some controversy, since authors regard the process as rapid, and proven to exist, others claim, largely on the basis of measurement of fluorescence anistropy, that it does not occur at all. We have synthesized two copolymer systems in an attempt to devise a more definitive experiment with which to test these conflicting hypotheses. These are polystyrene copolymerized with 0.01 percent of 2,5-diphenyl oxazole (PPO), and styrene-butadiene block copolymers.

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Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1982
Accession Number
ADA187148

Entities

People

  • David F. Phillips

Organizations

  • Royal Institution

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Alkenes
  • Block Copolymers
  • Chemical Analysis
  • Chromophores
  • Contracts
  • Copolymers
  • Dielectric Polymers
  • Emission
  • Emission Spectra
  • Energy
  • Energy Transfer
  • Fluorescence
  • Polymers
  • Polystyrenes
  • Spectroscopy
  • Styrenes
  • Synthetic Polymers

Fields of Study

  • Chemistry

Readers

  • Polymer Science and Technology
  • Theoretical Analysis.

Technology Areas

  • Microelectronics