The Synthesis, Characterization and Structural Studies of In(C5H4Me) by X-Ray Diffraction and Electron Diffraction Techniques and a Reinvestigation of the Crystalline State of In(C5H5) by X-Ray Diffraction Studies.

Abstract

The compound In(C5H4Me) has been prepared from InC1 and Li(C5H4Me) in diethyl ether and fully characterized according to its physical and solubility properties, reaction with dilute HC1, a cryoscopic molecular weight study in cyclohexane, infrared and 1H NMR spectroscopic properties, an X ray structural study and a gas-phase electron diffraction study. In addition, a quantitative X ray structural study has been used to reinvestigate the nature of the solid state of In(C5H5). The compound In(C5H4Me) crystallizes in the centrosymmetric space group P21/n (N0. 14var) with a = 6.1636(14), b = 11.5684(17), c = 9.1723(15)A, beta = 103.561(15), V = 635.78(19)A3 and Z = 4. Organoindium chemistry, Indium compounds, Chemistry, X ray structural studies, Electron diffraction studies, Cyclopentadienyl.

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Document Details

Document Type
Technical Report
Publication Date
Dec 17, 1987
Accession Number
ADA189110

Entities

People

  • J. C. Pazik
  • James C Fettinger
  • Melvyn Rowen M.R. Churchill
  • O. T. Beachley Jr.
  • T. E. Glassman

Organizations

  • University at Buffalo

Tags

Communities of Interest

  • C4I
  • Weapons Technologies

DTIC Thesaurus Topics

  • Alkanes
  • Chemistry
  • Crystal Lattices
  • Crystal Structure
  • Crystals
  • Diffraction
  • Diffractometers
  • Electron Diffraction
  • Electrons
  • Materials
  • Measurement
  • Military Research
  • Molecular Structure
  • Molecular Weight
  • Scattering
  • X Rays
  • X-Ray Diffraction

Fields of Study

  • Chemistry
  • Materials science

Readers

  • Materials Science and Engineering.
  • Organic Chemistry

Technology Areas

  • Microelectronics
  • Space