SiO2 Film Stress Distribution During Thermal Oxidation of Si.

Abstract

A laser reflection technique is used to investigate the relaxation of Silicon dioxide film stress which occurs during the dry thermal oxidation of Silicon between 700 and 1000 C. Included is a determination of the stress distribution in the oxide by two independent methods: 1) measurement on oxides of various thicknesses from 100 to 800 A, and 2) repeated stress measurements on chemically thinned SiO2 films, viz. etch back analysis toward the interface. Agreement is found between these experiments. These thin film stress measurements are achieved by the use of ultra-thin Si substrates 75 micrometers). Essentially, an increase in film stress with decreasing film thickness is observed. Rapid stress relaxation is observed for all temperatures studied and is attributed to a time-dependent oxide viscosity. The influence of these measured properties on the kinetics of Si oxidation is discussed.

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Document Details

Document Type
Technical Report
Publication Date
Dec 03, 1987
Accession Number
ADA189552

Entities

People

  • E. Kobeda
  • Eugene A. Irene

Organizations

  • University of North Carolina at Chapel Hill

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Chemistry
  • Classification
  • Diffusion
  • Equations
  • Films
  • Heat Of Activation
  • High Temperature
  • Low Temperature
  • Measurement
  • Military Research
  • North Carolina
  • Oxidation
  • Oxides
  • Relaxation Time
  • Silicon Dioxide
  • Thin Films
  • Viscous Flow

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Thin Film Deposition Science.

Technology Areas

  • Directed Energy
  • Directed Energy - Pulsed-Laser Deposition