Spectroscopy of Non-Agglomerated Particles in the Condensed Phase

Abstract

Because the optical properties of very small particles are frequently dominated by almost-unavoidable clustering of particles, this work has attempted to study the spectroscopy of systems of particles growing from one atom through multi-atom clusters to small particles. The techniques used are (1) low temperature matrix isolation spectroscopy in solid argon, and (2) in situ study of metal particles produced and growing in an inert gas. In order to help clarify the issue regarding the size regime at which bulk optical properties cease to be a valid approximation for increasingly small particles, Part I surveys this question, based both on the present results and on the work of many authors published in the open literature. Part II gives more specific details on the matrix isolation and gas phase spectroscopy.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Feb 01, 1988
Accession Number
ADA190662

Entities

People

  • Donald R. Huffman

Organizations

  • University of Arizona

Tags

Communities of Interest

  • Advanced Electronics
  • Biomedical

DTIC Thesaurus Topics

  • Absorption Spectra
  • Chemical Synthesis
  • Chemistry
  • Crystal Structure
  • Energy Bands
  • Low Temperature
  • Measurement
  • Optical Properties
  • Optics
  • Particle Size
  • Particles
  • Refraction
  • Refractive Index
  • Scattering
  • Spectra
  • Spectroscopy
  • Surface Plasmon Resonance

Fields of Study

  • Physics

Readers

  • Quantum Chemistry
  • Theoretical Analysis.
  • Thin Film Deposition Science.