Molecular Reaction and Energy Transfer Rate Estimation for Chemical-Laser Analysis.

Abstract

This report presents the results of an investigation of methods for estimation of reaction and energy transfer rates for collisions between electronically excited atoms and molecules of the sort typically present in energetic gases such as electronic-transition chemical laser media. The research specifically dealt with ground and excited-state electronic structure and energies of molecular collision complexes. The primary result of the investigation is a systematic method, within the context of electronic-structure theory, for estimation of potential energy surfaces for molecules in electronically excited states. Keywords: Molecular collisions, Interaction energies, Molecular reaction dynamics, Electronically excited atoms.

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Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1987
Accession Number
ADA190664

Entities

People

  • C. L. Beckel
  • J. C. Bellum

Organizations

  • University of New Mexico

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Angular Momentum
  • Atomic Orbitals
  • Atomic Structure
  • Atoms
  • Chemical Lasers
  • Chemical Reactions
  • Dynamics
  • Electron Energy
  • Electrons
  • Energy
  • Energy Transfer
  • Exclusion Principle
  • Ground State
  • Molecules
  • Potential Energy
  • Transitions
  • Wave Functions

Fields of Study

  • Physics

Readers

  • Molecular Photonics/Laser Physics
  • Quantum Chemistry
  • Regression Analysis.

Technology Areas

  • Directed Energy
  • Microelectronics