Reactions of Organometallic Compounds with Phosphorus (V) Esters and Related Species.

Abstract

The pentacoordinate phosphorus (V) hydride cyclenphosphorane has been treated with a variety of transition metal carbonyls. The first examples of lamda3-metallo-bis(methylene) phosphoranes and metal free phosphorus (V) hydrides have been produced. Unstable aryl-substituted metaphosphate moieties, ArOPO2, have been produced in the gas phase. Phosphavinylidenes have been found to undergo both facile electrophilic and nucleophilic attack. The synthetic usefulness of phosphaalkynes has also been explored. (Organic phosphorus compounds)

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Nov 30, 1987
Accession Number
ADA190893

Entities

People

  • Alan H. Cowley

Organizations

  • University of Texas at Austin

Tags

DTIC Thesaurus Topics

  • Alkenes
  • Carbonyl Complexes
  • Chemical Synthesis
  • Chemistry
  • Classification
  • Coordination Complexes
  • Crystal Structure
  • Electron Donors
  • Metals
  • Organic Chemistry
  • Organometallic Compounds
  • Organophosphorus Compounds
  • Phosphine
  • Phosphorus Compounds
  • Reactivities
  • Transition Metals
  • X Rays

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry