A Scientific Basis for an Alternate Cathode Architecture.
Abstract
The main effort of this research has been to try to bring together in a simplified manner both theoretical and experimental studies basic to the analysis of thermionic emission from Impregnated Dispenser Cathodes (IDC) as it is understood at this time. This study revealed two major areas of uncertainty: (1) the electronic and steric nature of the cathode emissive surface, and (2) the lack of a reproducible impregnation procedure. Mossbauer Spectroscopy was used to probe cathode surfaces and revealed that enhanced thermionic emission was concomitant with the presence of a low-spin state transition metal ion. The existence of the low-spin Mossbauer probe led to a formulation of a hypothetical surface considerations. This model had a striking parallelism with similar systems in the field of heterogeneous supported catalysis (HSC), viz., the hexagonal barium titanates (HBT). Keywords: Thermionic emission, Mossbauer spectroscopy, Differential thermal analysis, Crystal field theory, Metal metal bond.
Document Details
- Document Type
- Technical Report
- Publication Date
- Feb 01, 1988
- Accession Number
- ADA191498
Entities
People
- E. J. Daniszewski
Organizations
- Rome Laboratory