An Investigation of Microbiologically Mediated Corrosion of Copper-Nickel Piping Systems Selectively Treated with Ferrous Sulfate

Abstract

Microbiologically induced corrosion in 90/10 Cu-Ni pipes was evaluated using estuarine water from the Gulf of Mexico at the mouth of the Pascagoula River, maintained at a flow rate of 3-6 ft/sec over an 8-month period. The impact of surface preparation, batch FeSO4 (50 ppb Fe2+ for 48 hours) pretreatment and intermittent treatment was evaluated. Surface deposits were characterized by scanning electron microscopy and energy-dispersive x-ray fluorescence spectrometry. Water analyses included pH, dissolved oxygen, dissolved sulfide and sulfate, total organic carbon, total suspended solids and dissolved heavy metal analyses, as well as quantification of bacteriological components. Batch FeSO4 treatment did not result in a persistent increase in surface-bound iron or decreased localized corrosion. Surface pitting appeared to be associated with accumulations of chlorine, sulfur, and microbiological colonization.

Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1987
Accession Number
ADA191844

Entities

People

  • Brenda J. Little
  • Louis Janus
  • Patricia Wagner

Organizations

  • United States Naval Research Laboratory

Tags

DTIC Thesaurus Topics

  • Chlorine
  • Corrosion
  • Electron Microscopy
  • Electrons
  • Flow Rate
  • Fluorescence
  • Heavy Metals
  • Metals
  • Microscopy
  • Optical Analysis
  • Pipes
  • Piping Systems
  • Scanning Electron Microscopy
  • Water Analysis
  • X Rays

Fields of Study

  • Environmental science

Readers

  • Environmental Engineering
  • Materials Science and Engineering.
  • Molecular and Cellular Biochemistry

Technology Areas

  • Microelectronics