An In-Situ Ellipsometric Study of Aqueous NH4OH Treatment of Silicon.

Abstract

In-situ ellipsometry is used to analyze silicon surfaces in an aqueous ammonium hydroxide ambient. The ellipsometric data indicate that a surface which is optically quite similar to bare silicon is obtained when the native silicon dioxide film is etched from a Si substrate by aqueous NH4OH. In contrast, the surface obtained by etching the native oxide in aqueous buffered hydrogen fluoride leads to formation of a residual film on the Si substrate. Roughening of sample surfaces treated with either aqueous NH4OH or BHF is observed by microscopy. The high degree of roughness obtained following NH4OH treatment appears to influence ellipsometric measurements on samples, but this influence is not observed following BHF exposure where less roughness is noted.

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Document Details

Document Type
Technical Report
Publication Date
Mar 25, 1988
Accession Number
ADA192752

Entities

People

  • Eugene A. Irene
  • G. Gould

Organizations

  • University of North Carolina at Chapel Hill

Tags

DTIC Thesaurus Topics

  • Chemistry
  • Contrast
  • Films
  • Gas Evolution
  • Hydroxides
  • Measurement
  • Microscopy
  • Military Research
  • North Carolina
  • Oxide Films
  • Oxides
  • Refractive Index
  • Residuals
  • Roughness
  • Silicon
  • Substrates
  • Surface Roughness

Readers

  • Analytical Chemistry
  • Thin Film Deposition Science.