Piezoelectric Properties and Temperature Stability of Poly (Vinylidene Fluoride-Trifluoroethylene) Copolymers.

Abstract

Piezoelectric measurements were made on several copolymers of vinylidene fluoride and trifluoroethylene having a vinylidene fluoride concentration in the range of 65 to 75%. The hydrostatic g constant showed only a slight dependence on pressure, and pressures up to 35 MPa caused no apparent loss of the piezoelectric activity. A significant increase in the value of the hydrostatic g constant occurred with an increase in temperature. Anomalous results obtained upon cooling below room temperature may be attributed to the glass transition temperature of the trifluoroethylene comonomer. Temperature aging studies were performed at high temperatures using films of these copolymers. A significant loss of piezoelectric activity occurred after long time exposure. Isothermal studies at various aging temperatures revealed that this decay continued over a long time span. The aging behaviour characteristically followed a linear dependence on the logarithm of aging time. Keywords: Piezoelectric measurements; Vinylidene fluoride copolymers; Temperature stability.

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Document Details

Document Type
Technical Report
Publication Date
Jun 11, 1986
Accession Number
ADA193581

Entities

People

  • G. M. Stack
  • R. Y. Ting

Organizations

  • United States Naval Research Laboratory

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Classification
  • Dielectric Permittivity
  • Films
  • Glass
  • Glass Transition Temperature
  • Governments
  • High Temperature
  • Hydrostatic Pressure
  • Low Temperature
  • Materials
  • Measurement
  • Military Research
  • Polymers
  • Recognition
  • Static Pressure
  • Transition Temperature
  • Underwater Sound

Readers

  • Materials Science and Engineering.
  • Mathematics or Statistics
  • Thermal Physics or Thermal Science.

Technology Areas

  • Microelectronics