A Comparative Evaluation of Some Ortho Directing Groups for Cubane

Abstract

We have carried out a computational assessment of the relative ortho directing powers of four different functional groups in terms of their tendencies to interact with an adjacent lithium substituent, thereby producing a channel of strongly negative electrostatic potential leading to the lithiated (ortho) carbon. In terms of the factors examined in this analysis, it appears that the nitro group should have at least a moderate ortho-directing capability.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1988
Accession Number
ADA196826

Entities

People

  • Jack Alster
  • Keerthi Jayasuriya
  • Peter Politzer

Organizations

  • University of New Orleans

Tags

Communities of Interest

  • Air Platforms

DTIC Thesaurus Topics

  • Abstracts
  • Chemistry
  • Classification
  • Electrons
  • Engineering
  • Geometry
  • Military Research
  • Molecules
  • New Jersey
  • New York
  • Organic Chemistry
  • Physical Properties
  • Security
  • Test And Evaluation
  • Triangles
  • Universities

Readers

  • Battery Technology and Engineering
  • Quantum Chemistry
  • Systems Analysis and Design