Kinetics of Complexation of Lithium Perchlorate with 18-Crown-6 in Propylene Carbonate

Abstract

The kinetics of complexation of LiC104 with the macrocycle 18-crown-6 have been studied in propylene carbonate using ultrasonic relaxation techniques. Two concentration-independent relaxations are observed and explained in terms of the Eigen-Winkler mechanism. The influence of propylene carbonate on the complexation of lithium with crowns is compared with the influence of other aprotic solvents.

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Document Details

Document Type
Technical Report
Publication Date
Jun 30, 1988
Accession Number
ADA196943

Entities

People

  • D. E. Johnson
  • D. J. Rose
  • D. P. Cobranchi
  • E. M. Eyring
  • G. R. Phillips
  • R. M. Barton
  • S. Petrucci

Organizations

  • University of Utah

Tags

DTIC Thesaurus Topics

  • Absorption
  • Alcohols
  • Carbonate Esters
  • Carbonates
  • Chemical Compounds
  • Chemical Kinetics
  • Chemical Synthesis
  • Chemistry
  • Crown Ethers
  • Frequency
  • Lasers
  • Lithium Batteries
  • Military Research
  • Organic Chemistry
  • Perchlorates
  • Physical Chemistry
  • Universities

Fields of Study

  • Chemistry

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Organic Chemistry